Publications
* denotes equal contribution
* denotes equal contribution
26. Reid, A. G.; Moberg, M. E.; Koellner, C. A.; Machan, C. W.; Thornton, D. A.; Dickenson, J. C.; Stober, J. J.; Turner, D. A.; Tarring, T. J.; Brown, C. A.; Harrison, D. P. “Sterically Attenuated Electronic Communication in Cobalt Complexes of Meridional Isoquinoline-Derived Ligands for Applications in Electrocatalysis.” J. Chem. Phys. 2023, 159, 194306.
25. Benseghir, Y.; Solé-Daura, A.; Cairnie, D. R.; Robinson, A. L.; Duguet, M.; Mialane, P.; Gairola, P.; Gomez-Mingot, M.; Fontecave, M.; Iovan, D.; Bonnett, B.; Morris, A. J.; Dolbecq, A.; Mellot-Draznieks, C. “Unveiling the mechanism of the photocatalytic reduction of CO2 to formate promoted by porphyrinic Zr-based metal-organic frameworks.” J. Mater. Chem. A 2022, 10, 18103-18115.
24. Sahoo, D.; Iovan, D. A. “Toward understanding highly electron-withdrawing terminal Fe(IV) imides.” Chem 2021, 7, 1701-1702.
23. Dickenson, J. C.; Haley, M. E.; Hyde, J. T.; Reid, Z. M.; Tarring, T. J.; Iovan, D. A.; Harrison, D. P. “Fine-Tuning Metal and Ligand-Centered Redox Potentials of Homoleptic Bis-Terpyridine Complexes with 4′-Aryl Substituents.” Inorg. Chem. 2021, 60, 9956-9969.
Previous Publications
22. Derrick, J. S.; Loipersberger, M.; Chatterjee, R.; Iovan, D. A.; Smith, P. T.; Chakarawet, K.; Yano, J.; Long, J. R.; Head-Gordon, M.; Chang, C. J. “Metal–ligand cooperativity via exchange coupling promotes iron-catalyzed electrochemical CO2 reduction at low overpotentials.” J. Am. Chem. Soc. 2020, 142, 20489-20501.
21. Toh, J. D. W.; Crossley, S. W. M.; Bruemmer, K. J.; Ge, E. J.; He, D.; Iovan, D. A.; Chang, C. J. “Distinct RNA N-demethylation pathways catalyzed by nonheme iron ALKBH5 and FTO enzymes enable regulation of formaldehyde release rates.” Proc. Natl. Acad. Sci. 2020, 117, 25284-25292.
20. Sedgwick, A. C.; Brewster, J. T.; Harvey, P.; Iovan, D. A.; Smith, G.; He, X.-P.; Tian, H.; Sessler, J. L.; James, T. D. “Metal-based imaging agents: progress towards interrogating neurodegenerative disease.” Chem. Soc. Rev. 2020, 49, 2886-2915.
19. Carsch, K. M.; Lukens, J. T.; DiMucci, I. M.; Iovan, D. A.; Zheng, S.-L.; Lancaster, K. M.; Betley, T. A. “Electronic structures and reactivity profiles of aryl nitrenoid-bridged dicopper complexes.” J. Am. Chem. Soc. 2020, 142, 2264–2276.
18. Ohata, J.; Krishnamoorthy, L.; Gonzalez, M. A.; Xiao, T.; Iovan, D. A.; Toste, F. D.; Miller, E. W.; Chang, C. J. “An Activity-based methionine bioconjugation approach to developing proximity-activated imaging reporters.” ACS Cent. Sci. 2020, 6, 32-40.
17. Carsch, K. M.; DiMucci, I. M.; Iovan, D. A.; Li, A.; Zheng, S.-L.; Titus, C. J.; Lee, S. J.; Irwin, K. D.; Nordlund, D.; Lancaster, K. M.; Betley, T. A. “Synthesis of a copper–supported triplet nitrene complex pertinent to copper–catalyzed amination.” Science 2019, 365, 1138-1143.
16. Iovan, D. A.*; Jia, S.*; Chang, C. J. “Inorganic chemistry approaches to activity-based sensing: from metal sensors to bioorthogonal metal chemistry.” Inorg. Chem. 2019, 58, 13546–13560.
15. Bartholomew, A. K.; Teesdale, J. J.; Hernández Sánchez, R.; Malbrecht, B. J.; Juda, C. E.; Ménard , G.; Bu, W.; Iovan, D. A.; Mikhailine, A. A.; Zheng, S.-L.; Sarangi, R.; Wang, S. G.; Chen, Y.-S.; Betley, T.A. “Exposing the inadequacy of redox formalisms by resolving redox inequivalence within isovalent clusters.” Proc. Natl. Acad. Sci. 2019, 116, 15836–15841.
14. Iovan, D. A.; Wilding, M. J. T.; Baek, Y.; Hennessy, E. T.; Betley, T. A. “Diastereoselective C–H bond amination for disubstituted pyrrolidines.” Angew. Chem. Int. Ed. 2017, 56, 15599–15602.
13. Iovan, D. A.; Wrobel, A. T.; McClelland, A. A.; Scharf, A. B.; Edouard, G. A.; Betley, T. A. “Reactivity of a stable copper–dioxygen complex.” Chem. Commun. 2017, 53, 10306–10309.
12. Wilding, M. J. T.; Iovan, D. A.; Wrobel, A. T.; Lukens, J. T.; MacMillan, S. N.; Lancaster, K. M.; Betley, T. A. “Direct comparison of C–H bond amination efficacy through manipulation of nitrogen-valence centered redox: imido versus iminyl.” J. Am. Chem. Soc. 2017, 139, 14757−14766.
11. Wilding, M. J. T.; Iovan, D. A.; Betley, T. A. “High spin iron imido complexes competent for C–H bond amination.” J. Am. Chem. Soc. 2017, 139, 12043–12049.
10. Delle Chiaie, K. R.; Biernesser, A. B.; Ortuño, M. A.; Dereli, B.; Iovan, D. A.; Wilding, M. J. T.; Li, B.; Cramer, C. J.; Byers, J. A. “The role of ligand redox non-innocence in ring-opening polymerization reactions catalysed by bis(imino)pyridine iron alkoxide Complexes.” Dalton Trans. 2017, 46, 12971–12980.
9. Culcu, G.; Iovan, D. A.; Krogman, J. P.; Wilding, M. J. T.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. “Heterobimetallic complexes comprised of Nb and Fe: isolation of a coordinatively unsaturated NbIII/Fe0 bimetallic complex featuring a Nb≡Fe triple bond.” J. Am. Chem. Soc. 2017, 139, 9627– 9636.
8. Iovan, D. A.; Betley, T. A. “Characterization of iron-imido species relevant for N-group transfer chemistry.” J. Am. Chem. Soc. 2016, 138, 1983–1993.
7. Pranckevicius, C.; Iovan, D. A.; Stephan, D. W. “Three and four coordinate Fe carbodiphosphorane complexes.” Dalton Trans. 2016, 45, 16820–16825.
6. Lankenau, A. W.; Iovan, D. A.; Pienkos, J. A.; Salomon, R. J.; Wang, S.; Harrison, D. P.; Myers, W. H.; Harman, W. D. “Enantioenrichment of a tungsten dearomatization agent utilizing chiral acids.” J. Am. Chem. Soc. 2015, 137, 3649–3655.
5. Hennessy, E. T.; Liu, R. Y.; Iovan, D. A.; Duncan, R. A.; Betley, T. A. “Iron-mediated intermolecular N-group transfer chemistry with olefinic substrates.” Chem. Sci. 2014, 5, 1526–1532.
4. Pienkos, J. A.; Zottig, V. E.; Iovan, D. A.; Li, M.; Harrison, D. P.; Sabat, M.; Salomon, R. J.; Strausberg, L.; Teran, V. A.; Myers, W. H.; Harman, W. D. “Friedel–Crafts ring-coupling reactions promoted by tungsten dearomatization agent.” Organometallics 2013, 32, 691–703.
3. Harrison, D. P.; Iovan, D. A.; Myers, W. H.; Sabat, M.; Wang, S.; Zottig, V. E.; Harman, W. D. “[4 + 2] Cyclocondensation reactions of tungsten-dihydropyridine complexes and the generation of tri- and tetrasubstituted piperidines.” J. Am. Chem. Soc. 2011, 133, 18378–18387.
2. Harrison, D. P.; Nichols-Nielander, A. C.; Zottig, V. E.; Strausberg, L; Salomon, R. J.; Trindle, C. O.; Sabat, M.; Gunnoe, T. B.; Iovan, D. A.; Myers, W. H.; Harman, W. D. “Hyperdistorted tungsten allyl complexes and their stereoselective deprotonation to form dihapto-coordinated dienes.” Organometallics 2011, 30, 2587–2597.
1. Burke, J. P.; Sabat, M.; Iovan, D. A.; Myers, W.H.; Chruma, J. J. “Exploring the original proposed biosynthesis of (+)-symbioimine: remote exocyclic stereocontrol in a type I IMDA reaction.” Org. Lett. 2010, 12, 3192–3195.
Virginia Tech
Department of Chemistry
Blacksburg, VA 24060
Department of Chemistry
Blacksburg, VA 24060